Email this article Kinetic Probe of Azure-b Eosin Y Reaction with Thiourea in an Acid Medium
Abstract
Kinetic probe of the azure-b eosin Y reaction with thiourea in an acid medium was executed using a spectrophotometric approach at 299 K. The reaction proceeded with the active form eosin Y that was actualized by deprotonation, leading to a decrease in reaction rate with the elevation of acid concentration. The reaction assumed a 1:1 stoichiometry (EY: TU) with the inclusion of free radical species. The concentration of the reaction species assumed first order kinetics. The reaction rate elevation was experienced in increasing the ionic strength and was decelerated as the medium polarity was altered with acetone. This demonstrated the effect of ion species distribution at the rate-controlling phase. There was a glaring catalytic effect on the inclusion of additional ion (Mg2+) to the system. The involvement of a steady intermediate moiety was ruled out as shown by kinetic evidence from the Lineweaver-Burk modification of the Michaelis-Menten plot.
Full Text:
PDFReferences
El-Sikaily A, Khaled A, El Nemr A (2012) Textile dyes xenobiotic and their harmful effect. In, pp. 31-64
Zheng H, Pan Y, Xiang X (2007) Oxidation of acidic dye eosin Y by the solar photo-fenton processes. J Hazard Mater 141(3):457-464
Mitra S, Ghosh M, Mishra S, Hajra A (2015) Metal-free thiocyanation of imidazoheterocylces through visible light photoredox catalysis. J Org Chem 80(16):8275–8281
Srivastava V, Singh PK, Singh PP (2015) Eosin Y catalyzed visible-light-promoted aerobic oxidative cyclization of 2-aminobenzothizole. Croat Chem Acta 88(3):227–233
Song C, Chen P, Tang Y (2017) Carboxylation of styrenes with CBr4 and DMSO via cooperative photoredox and cobalt catalysis. RSC Adv 7(19):11233–11243
Majek M, Wangelin AJ (2014) Metal-free carbonylations by photoredox catalysis. Angew Chem Int Ed 54(7):2270-2274
Gazi S, Ananthakrishnan R (2011) Metal-free-photocatalytic reduction of 4-nitrophenol by resin-supported dye under the visible irradiation. Appl Catal B 105:317–325
Yang D, Meng Q, Zhong J, Xiang M, Liu Q, Wu L (2013) Metal-free desulfonylation reaction through visible light photoredox catalysis. Eur J Org Chem 2013(33):7528–7532
Neumann M, Füldner S, König B, Zeitler K (2011) Metal-free, cooperative asymmetric organophotoredox catalysis with visible light. Angew Chem Int Ed 50:951–954
Yan DY, Zhao Q, Rao L, Chen J, Xiao W (2018) Eosin Y as a redox catalyst and photosensitizer for sequential benzylic C-H amination and oxidation, Chem Eur J 24(63):16895-16901
Wang S, Lin J, Chen F, Hu M, Hu X, Han Y, Gao Q (2004) Kinetics and mechanism of the reaction between thiourea and iodate in unbuffered medium. Sci China Series B: Chem 47:480–491
Ni S, Bai F, Pan X (2020) Atmospheric chemistry of thiourea: nucleation with urea and roles in NO2 hydrolysis. Phys Chem Chem Phys 22(15):8109–8117
Naz S, Zahoor M, Umar MN, Alghamdi S, Sahibzada MUK, UlBari W (2020) Synthesis, characterization, and pharmacological evaluation of thiourea derivatives. Open Chem 8:764–773
Sahu S, Sahoo PR, Patel S, Mishra BK (2011) Oxidation of thiourea and substituted thioureas: a review. J Sulphur Chem 32(2):171–197
Mohite AR, Phatake RS, Dubey P, Agbaria M, Shames AI, Lemcoff Ng, Reany O (2020) Thiourea-mediated halogenation of alcohols. J Org Chem 85(20):12901–12911
Saad IR, Abdel-Gaber AM, Younes GO, Nsouli B (2018) Thiourea and n-methylthiourea as corrosion inhibitors for steel in phosphoric acid. J Fail Anal Preven 18(5):1293–1299
So H., Lee H, Lee GD, Kim M, Lim MH, Kim K, Kim C (2020) A thiourea-based fluorescent chemosensor for bioimaging hypochlorite. J Ind Eng Chem 89:436–441
Azizi N, Farhadi E (2017) Rapid and highly efficient synthesis of thioureas in biocompatible basic choline hydroxide. J Sulfur Chem 38(5):548–554
Kudrik EV, Theodoridis A, Eldik RV, Makarov SV (2005) Kinetics and mechanism of the Co(II)-assisted oxidation of thioureas by dioxygen. Dalton Trans 6:1117-1122
R´abai G, Wang RT, Kustin K (1993) Kinetics and mechanism of the oxidation of thiourea by chlorine dioxide. Int J Chem Kinet 25(1):53–62
Chatterjee D, Rothbart S, Eldik R (2013) Selective oxidation of thiourea with H2O2 catalysed by [RuIII(edta)(H2O)]: kinetic and mechanistic studies. Dalton Trans 13:4725–4733
Nkole, I.U., Idris, S.O., Onu, A.D. (2021) Redox reactions of tris-(1,10-phenanthroline)iron(III) complex with thiourea and N-methylthiourea in an aqueous acidic medium: kinetics and mechanism. Inorg Chem Comm 133:108930
Arthur, D.E., Nkole, I.U., Osunkwo, C.R. (2020) Electron transfer reaction of tris-(1,10‑phenanthroline)cobalt(III) complex and iodide ion in an aqueous acidic medium. Chem Afr 4(1):63-69
Abdulsalam, S., Idirs, S. O., Shallangwa G. A, Onu, A. D. (2020) Reaction of n, n1 -phenylenebis(salicyalideneiminato)cobalt(III) and l-cysteine in mixed aqueous medium: kinetics and mechanism. Heliyon 6 e04621
Gupta V, Carroll, K.S. (2014) Sulfenic acid chemistry, detection and cellular lifetime. BBA 1840 (2):847–875
Nkole, I.U., Osunkwo, C.R., Onu, A.D., Idris, S.O. (2018) Kinetics and mechanism of the reduction of n-(2-hydroxyethyl)ethylenediaminetriacetatoiron(III) complex by thioglycol in bicarbonate buffer medium. Int J Adv Chem 6(1):102-107
Acharya, S, Rebery, B. (2009) Fluorescence spectrometric study of eosin dye-surfactant interactions. Arabian J Chem 2(1):11-19
Nkole IU, Idris SO, Abdulkadir I, Onu AD (2022) Redox reaction of bis-(2-pyridinealdoximato)dioxomolybdate(IV) complex with thiosulphate ion in aqueous acidic and surfactant media. Inorg Chem Comm 140:109468
Dennis CR, Van Zyl GJ, Fourie E, Basson SS, Swarts JC (2021) A kinetic study of the oxidation of the tetrakisoxalatouranate(IV) ion by the hexacyanoferrate(III) ion in an oxalate buffer medium. Reac Kinet Mech Catal 132:599-615
Arthur DE, Nkole IU, Osunkwo CR (2020) Electron transfer reaction of tris-(1,10‑phenanthroline)cobalt(III) complex and iodide ion in an aqueous acidic medium. Chem Afr 4(1):63-69
Idris SO, Suleiman JO, Iyun JF, Osunlaja AA (2015) Reduction of 3,7-bis(dimethylamino)phenazothionium chloride by benzene thiol in aqueous nitric acid medium: a mechanistic approach. Am Chem Soc J 5(4):313-321
Ibrahim I, Idris SO, Abdulkadir I, Onu AD (2019) Kinetics and mechanism of the redox reaction of n, n1-phenylenebis-(salicylideneiminato)iron(III) with oxalic acid in mixed aqueous medium. Transit Met Chem 44(3):269-273
Nkole IU, Idris SO (2021) Thermodynamics and kinetic investigation of reaction of acriflavine with l-cysteine in aqueous medium. Chem Afr 4:731-740
Nkole, I.U., Idris, S.O., Onu, A.D., Abdulkadir, I. (2022) The study of piszkiewicz’s and berezin’s models on the redox reaction of allylthourea and bis-(2-pyridinealdoximato)dioxomolybdate(IV) complex in an aqueous acidic medium. Beni-Suef Uni J Basic Appl Sci 11:68
Refbacks
- There are currently no refbacks.