Solvothermal Synthesis of Secondary Phase Free Copper Zinc Tin Selenide (CZTSe) Nanoparticles for Thin Film Fabrication
Abstract
The current study provides an effective solvothermal synthesis of copper zinc tin selenide (CZTSe) nanoparticles for thin film fabrication. CZTSe nanoparticles were synthesized via a solvothermal route and were allowed to cool at room temperature with different cooling durations ranging from 24 to 96 hours. The results obtained from the X-ray diffraction analysis and Raman spectroscopy revealed that the synthesized CZTSe which are allowed to cool for 72 hours shows the highest quality of sample without any impurities. The results show that the 72 hours is the optimum period to allow proper solution reaction to occur. The morphological properties and chemical components of the CZTSe nanoparticles were equally presented.
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Ahmadi, M., Pramana, S. S., Xi, L., Boothroyd, C., Lam, Y. M., & Mhaisalkar, S. (2012). Evolution pathway of CIGSe nanocrystals for solar cell applications. Journal of Physical Chemistry C, 116(14), 8202–8209. https://doi.org/10.1021/jp300187r
Chandel, T., Zaman, M. B., Basu, N., Lahiri, J., & Poolla, R. (2018). Growth and properties of solvothermally derived CZTSe nanocrystals using elemental precursors. Physica B: Condensed Matter, 545, 262–267. https://doi.org/10.1016/j.physb.2018.06.031
Delgado-Sanchez, J. M., & Lillo-Bravo, I. (2022). High Vapor Transport Deposition: A Novel Process to Develop Cu2ZnSn(SxSe1–x)4 Thin Film Solar Cells. Solar RRL, 6(2). https://doi.org/10.1002/solr.202100835
Djemour, R., Redinger, A., Mousel, M., Gütay, L., Fontané, X., Izquierdo-Roca, V., Pérez-Rodríguez, A., & Siebentritt, S. (2013). The three A symmetry Raman modes of kesterite in Cu_2ZnSnSe_4. Optics Express, 21(S4), A695. https://doi.org/10.1364/oe.21.00a695
Du, Y. F., Zhou, W. H., Zhou, Y. L., Li, P. W., Fan, J. Q., He, J. J., & Wu, S. X. (2012). Solvothermal synthesis and characterization of quaternary Cu 2ZnSnSe 4 particles. Materials Science in Semiconductor Processing, 15(2), 214–217. https://doi.org/10.1016/j.mssp.2011.09.005
Engberg, S., Li, Z., Lek, J. Y., Lam, Y. M., & Schou, J. (2015). Synthesis of large CZTSe nanoparticles through a two-step hot-injection method. RSC Advances, 5(117), 96593–96600. https://doi.org/10.1039/c5ra21153k
Hasan, M. M., & Chowdhury, M. I. B. (2018). Modelling and Analysis of CdS/CZTSSe Based Thin Film Solar Cell. Journal of Modeling and Optimization, 10(2), 88. https://doi.org/10.32732/jmo.2018.10.2.88
Just, J., Sutter-Fella, C. M., Lützenkirchen-Hecht, D., Frahm, R., Schorr, S., & Unold, T. (2016). Secondary phases and their influence on the composition of the kesterite phase in CZTS and CZTSe thin films. Physical Chemistry Chemical Physics, 18(23), 15988–15994. https://doi.org/10.1039/c6cp00178e
Lee, P. Y., Shei, S. C., & Chang, S. J. (2013). Evolution pathways for the formation of Nano-Cu2ZnSnSe 4 absorber materials via elemental sources and isophorondiamine chelation. Journal of Alloys and Compounds, 574, 27–32. https://doi.org/10.1016/j.jallcom.2013.03.254
Liang, Y., Zeng, C., Zeng, L., Yan, G., Yuan, Y., Lin, X., Zhu, H., Mai, Y., & Hong, R. (2022). Effect of Self-Seed Inducing on the Growth Mechanism and Photovoltaic Performance of Cu2ZnSnSe4 Thin Films. Solar RRL, 6(4). https://doi.org/10.1002/solr.202101047
Liu, K., Ji, N., Shi, L., & Liu, H. (2014). The phase and morphology of Cu2ZnSnSe4 nanopowders by hydrothermal method. Journal of Nanomaterials, 2014. https://doi.org/10.1155/2014/910639
Matsushita, H., Maeda, T., Katsui, A., & Takizawa, T. (2000). Thermal analysis and synthesis from the melts of Cu-based quaternary compounds Cu-III-IV-VI4 and Cu2-II-IV-VI4 (II = Zn, Cd; III = Ga, In; IV = Ge, Sn; VI = Se). Journal of Crystal Growth, 208(1–4), 416–422.
Nag, A., Kovalenko, M. V., Lee, J. S., Liu, W., Spokoyny, B., & Talapin, D. V. (2011). Metal-free inorganic ligands for colloidal nanocrystals: S2-, HS-, Se2-, HSe-, Te2-, HTe -, TeS32-, OH-, and NH 2- as surface ligands. Journal of the American Chemical Society, 133(27), 10612–10620. https://doi.org/10.1021/ja2029415
Nakamura, M., Yamaguchi, K., Kimoto, Y., Yasaki, Y., Kato, T., & Sugimoto, H. (2019). Cd-Free Cu(In,Ga)(Se,S)2 thin-film solar cell with record efficiency of 23.35%. IEEE Journal of Photovoltaics, 9(6), 1863–1867. https://doi.org/10.1109/JPHOTOV.2019.2937218
Olekseyuk, I., Gulay, L., Dydchak, I., Piskach, L., Parasyuk, O., & Marchuk, O. (2002). Single crystal preparation and crystal structure of the Cu2Zn/ Cd,Hg/ SnSe4 compounds. Journal of Alloys and Compounds, 304, 141–145.
Raja, P., & Barron, A. (2022). Physical Methods in Chemistry and Nano Science. Libre Texts.
Simya, O. K., Geetha Priyadarshini, B., Balachander, K., & Ashok, A. M. (2020). Formation of a phase pure kesterite CZTSe thin films using multisource hybrid physical vapour deposition. Materials Research Express, 7(1). https://doi.org/10.1088/2053-1591/ab64ee
Vallejo, O. R., Sánchez, M., Pal, M., Espinal, R., Llorca, J., & Sebastian, P. J. (2016). Synthesis and characterization of nanoparticles of CZTSe by microwave-Assited chemical synthesis. Materials Research Express, 3(12). https://doi.org/10.1088/2053-1591/3/12/125017
Wang, C.-J., Shei, S.-C., & Chang, S.-J. (2014). Synthesis and characterization of CZTSe nanoinks using polyetheramine as solvent. Optical Materials Express, 4(8), 1593. https://doi.org/10.1364/ome.4.001593
Wu, L., Xiang, Y., & Sun, Y. (2016). Synthesis of Cu2ZnSnSe4 Nanoparticles via Solvothermal Route. 4th International Conference on Advanced Materials and Information Technology Processing (AMITP 2016), 499–502.
Zhang, Y.-M., Jia, Z.-J., & Zhao, Z.-Y. (2022). Secondary phases in Cu2ZnSnS4 thin film solar cell: The role of interfaces. Physica B: Condensed Matter, 626(1), 413539.
Zhou, B., Xia, D., & Wang, Y. (2015). Phase-selective synthesis and formation mechanism of CZTS nanocrystals. RSC Advances, 5(86), 70117–70126. https://doi.org/10.1039/c5ra11890e
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