Synthesis and Application of Dye Derived from Caesalpinia Coriaria (DIVI-DIVI) and Carbon Steel Waste Extract on Cotton

Magaji Y. I., Hassan S., Uwaiya E., Obasi O. Q., Pascalina L., Okeh A.

Abstract


Dye substances produced from the reaction of Caesalpinia coriaria (Divi-divi) and carbon steel waste extract, were assessed using FTIR, UV-Visible spectra, and fastness test on wash fastness, light fastness, rub fastness and fastness to ironing. Characteristic group absorption within 3200 cm-1 – 3400 cm-1 indicate hydrogen bond OH absorption usually broad while others in region 2900 cm-1 – 2000 cm-1 are attributed to CH3, CH2, CH, C =C stretch, and 1640 cm-1 – 1707 cm-1, 1440-1640 cm-1 are attributed to C=O stretch and C=C stretch respectively. The dye bath containing formic acid has a wavelength of 599 nm and an absorbance of 1.447 while the wavelength of Caesalpinia coriaria in an aqueous medium is 450nm and absorbance of 1.113. The wash fastness is 5, light fastness is 5, rub fastness for both wet and dry is 5, and fastness to ironing for wet and dry is 5. The following numbers represent the following: 5 for excellent, 4 for very good, 3 for good, 2 for fair and 1 for poor according to the grey scale for change of colour. The above result shows that the dye has a good fastness property and that it is suitable for application on cotton.


Full Text:

PDF

References


Ashis Kumar Samanta and Adwaita Konar (2011). Dyeing of textiles with natural dyes, natural dyes, Dr Emriye Akcakoca Kumbasar (Ed.), ISBN: 978-953-307-783-3, InTechnology, Available from: http://www.intechopen.com/books/natural-dyes/dyeing- of-textiles-with-natural-dyes

Ding Yi and Harold S. F. (2017). “Mordant dye Application on Cotton: Optimization and colonist, colour technology

Hem J.D. (1999). Complexes of Ferrous Iron with Tannic Acid, Chemistry at Iron in Natural Water. Geological Survey Water-Supply Paper 1459. United State Government Printing Office. Washington.

Kiazer, E. Jabalpurwala and Ronald M. Milburn (1996) “iron (iii) phenol complexes. II iron III and proton associations with some single substituted phenolate low at 25” journal of American chemical society

Okoli, C. A., Onukwuli, C.D., Okey-Onyesolu, C.E. and Okoye C.C., (2015). Adsorptive Removal of Dyes from Synthetic Wastewater using Activated Carbon from Tamarind Seed. European Scientific Journal, 11(18): 190-221.

OMRI (2002). Activated carbon processing. National Organic standards board of technical advisory panel review for the USDA. National Organic Program, 1-14.

Ozacar M. and Sengil I.A. (2003). Adsorption of reactive dyes on calcined alunite from aqueous solutions. Journal Hazardous Materials, 98: 211-224.

Palanisamy P. N., Agalya A. and Sivakumar P., (2013). Equilibrium uptake and sorption Dynamics for the Removal of Reactive Dyes from Aqueous Solution using Activated Carbon prepared from Euphobia tirucalli L wood. Indian Journal of Chemical Technology, 20: 245-251.

Pons, M. P. and Fuste, C. M. (1993). Uranium uptake by immobilized cells of pseudomonas strain. Journal of Applied Microbiology and Biotechnology, 39(4-5): 661-665.

Saswati G., and Uday C.G., (2005). Studies on adsorption behaviour of Cr(VI) onto synthetic hydrous stannic oxide. Water Resources (www.wrc.org.za), 13(4): 597-602

Shanthi and T. Mahalakshmi (2012) Studies on the Removal of Malachite Green and Methylene Blue Dyes from Aqueous Solutions of their Binary Mixture by Adsorption over Commercial Activated Carbon and Tamarind Kernel Powder. International Journal of Research in Pharmacy and Chemistry, 2 (2): 289-298

Sun, Q. and L. Yang, (2003).The Adsorption of Basic Dyes from Aqueous Solution on Modified Peat-Resin Particle. Elsevier Journal of Water Research, 37 (7): 1535.

Suresh, D. S., Thomas, K. A., Mohan, P. N., and Damodaran, A. D., (1994). Alteration of Ilmenite in the Manavalakurichi Deposit, India. Clays and Clay Minerals Journal, 42 (5): 567 - 571.

Saradhi, B.V., Rao, S.R.K., Kumar, Y.P., Vijetha, P., Rao, K.V., and Kalyami, G. (2010). Applicability of Langmuir and Freundlich theory for Biosorption of Chromium from Aqueous Solution using a test of Sea Urchins. International Journal of Chemical Engineering Research, 2(2): 139-148

Vijayakumar G., Tamilarasan R., and Dharmendirakumar M., (2012). Adsorption, Kinetic, Equilibrium and Thermodynamic studies on the removal of Basic Dye Rhodamine-B from aqueous solution by the use of natural Adsorbent. Journal of Material and Environmental Science, 3(1): 157-170.


Refbacks

  • There are currently no refbacks.